72128-38-2

Basic information

• Product Name: 2-formyl-2-cyclohexene-1-acetaldehyde
• Synonyms: 2-formyl-2-cyclohexene-1-acetaldehyde
• CAS NO: 72128-38-2
• Molecular Weight: 152.193
• Mol File: 72128-38-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-formyl-2-cyclohexene-1-acetaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-formyl-2-cyclohexene-1-acetaldehyde(72128-38-2)
• EPA Substance Registry System: 2-formyl-2-cyclohexene-1-acetaldehyde(72128-38-2)

Safety Data

• Hazardous Substances Data: 72128-38-2(Hazardous Substances Data)

Upstream product

• 72128-56-4 C₉H₁₄O₂ 
• 72128-56-4 C₉H₁₄O₂ 
• 72128-36-0 (1R*,5S*,8R*)-spirooctan-8,2'-oxirane>-6-one 
• 72128-36-0 (1R*,5R*,8S*)-spirooctane-8,2'-oxiran>-6-one 
• 72128-53-1 exo-8-oxobicyclo<3.2.1>octan-6-yl acetate 
• 72128-52-0 (1R*,5S*,8R*)-spirooct-6-en-8,2'-oxirane> 
• 72128-55-3 exo-8-methylenebicyclo<3.2.1>octan-6-ol 
• 22241-76-5 bicyclo[3.2.1]oct-6-en-8-one 
• 123849-00-3 cis-3-ethoxy-3,4,4a,5,6,7-hexahydro-8H-2-benzopyran-8-one 
• 94250-47-2 6-oxocyclohex-1-ene-1-carbaldehyde 

Relevant articles and documents

Stereo- and enantioselective routes to functionalised cyclohexenes via heterodiene cycloadditions of 6-oxocyclohexene-1-carbaldehydes with ketene acetals

Various substituted cyclohexenes related to α-cyclocitral have been prepared using the heterodiene cycloadditions of 2-formyl-4,4-dimethyl-2- cyclohexen-1-one 4 with ketene acetals as the pivotal step. The key intermediates are accessible in homochiral form via an auxiliary-based sequence in which a C2-symmetric ketene acetal derived from 1,2-bis(2- methylphenyl)ethane-1,2-diol 2a serves as the 2π component. The diol 2a can be recovered in optically pure form.