7215-33-0Relevant academic research and scientific papers
Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement
Renard, Pierre-Yves,Vayron, Philippe,Mioskowski, Charles
, p. 1661 - 1664 (2007/10/03)
(Matrix presented) We describe a new, straightforward, and easy-to-handle method for achieving an unprecedented trimethylsilyl halide-catalyzed Michaelis-Arbuzov-like rearrangement. This rearrangement occurs at temperatures from room temperature to 80°C and does not require addition of any alkyl halide. The scope and limitations of this new reaction are explored, as well as its mechanism.
Phosphosulfonate herbicides
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, (2008/06/13)
This invention pertains to phosphosulfonates, having the general formula STR1 wherein Y is phenyl, naphthyl, benzyl, a (C5 -C8)cycloalkyl, a 5-membered heteroaromatic ring, a 6-membered heteraromatic ring, a fused 5,6-membered heteroaromatic ring, or a fused 6,6-membered heteroaromatic ring; and X is oxygen or sulfur; and R1 and R2 are each independently selected from substituted or unsubstituted alkyl, alkoxy, alkylthio, alkenyloxy, alkynyloxy, haloalkoxy, cyanoalkoxy, alkoxyalkoxy, cycloalkyloxy, cycloalkylalkoxy, alkylideneiminooxy, chloro, amino, phenyl or phenoxy; or R1 and R2 are both alkoxy, taken together with the phosphorus atom to form a 6-membered oxygen-containing ring; compositions containing these compounds and their use as herbicides.
Kinetic Study of the Alkaline Hydrolysis of 2,2,2-Trichloro-1-hydroxyethyl Substituted Phosphinates and Phosphine Oxides
Aksnes, Gunnar,Larsen, Rolf Olaf
, p. 1967 - 1972 (2007/10/02)
The study shows that the alkaline hydrolysis of 2,2,2-trichloro-1-hydroxyethyl substituted phosphinates follows the same route as the corresponding phosphonates, Dipterex (1) and its ethyl analogue, giving O-P-C rearrangement products.The corresponding diphenyl and diethyl phosphine oxide derivatives 7 or 6, respectively, are hydrolyzed according to another reaction mechanism resulting in secondary phosphine oxides and dichloroacetic acid.
