72173-44-5Relevant academic research and scientific papers
Allylsilane-Based Annulations. Direct Stereoselective Syntheses of (+/-)-Graveolide and (+/-)-Aromaticin
Majetich, George,Song, Jee-Seop,Leigh, Alistair J.,Condon, Stephen M.
, p. 1030 - 1037 (2007/10/02)
An allylsilane-based annulation was used to construct a functionalized perhydroazulene.The C(1), C(5), and C(10) stereocenters, characteristic of the helenanolides, were established using a reductive alkylation strategy.Stereoselective syntheses of the pseudoguaianolides graveolide and aromaticin were achieved.
