72195-48-3Relevant academic research and scientific papers
Chemodivergent Synthesis of Allylic Sulfones via Ligand-Controlled Coupling of Allenes with Sulfinic Acids
Li, Ding-Chang,Zeng, Jia-Hao,Zhan, Zhuang-Ping,Zhang, Sheng
supporting information, (2022/02/09)
Allylic sulfones are important building blocks in organic synthesis and pharmaceutical chemistry. Herein, we disclose a chemodivergent protocol for Pd-catalyzed and ligand-controlled coupling of allenes with sulfinic acids, providing straightforward and atom-economical access to branched allylic sulfones and linear allylic sulfones bearing a conjugated (Z,E)-1,3-diene scaffold in good yields with high selectivities. This strategy features mild conditions, an unprecedented substrate scope, and functional group compatibility.
Synthesis of (+/-)-Lavandulol and its Related Homoallylic Alcohol via Allyl Transfer from Sulphur to Tin
Ueno, Yoshio,Aoki, Seiichi,Okawara, Makoto
, p. 683 - 684 (2007/10/02)
(+/-)-Lavandulol and related homoallylic alcohols were prepared by the stannolysis of allylic sulphones and the subsequent hydroxymethylation of the resulting allylic stannanes with trioxan-BF3*OEt2.
