72214-10-9Relevant articles and documents
Synthesis and properties of chlorine(I) and bromine(I) trifluoromethanesulfonates and Raman spectra of CF3SO2X (X = F, OH, OCl)
Katsuhara, Yutaka,Hammaker, Robert M.,DesMarteau, Darryl D.
, p. 607 - 615 (2008/10/08)
The synthesis and characterization of the new hypohalites CF3SO3Cl and CF3SO3Br are described. Both compounds are thermally unstable at 22°C, decomposing to CF3Cl and SO3 for the hypochlorite and CF3SO3CF3, CF3SO2OSO2OCF3, SO3 and Br2 for the hypobromite. The hypochlorite is prepared by reaction of CF3SO3H with ClF and the hypobromite by reaction of CF3SO3Cl with bromine. The low-temperature Raman spectrum of CF3SO3Cl suggests C1 symmetry and assignments of 20 of the expected 21 fundamentals are given. These assignments were aided by an analysis of the Raman spectra of CF3SO2F and CF3SO2OH, which are reported for the first time.