72299-83-3Relevant academic research and scientific papers
Regiospecific functionalisation of unsaturated compounds via their dilithio derivatives. Part 1: Reaction of dilithio compounds of 1-alkynes with epoxides, benzyl halides and trimethylchlorosilane
Hommes, H.,Verkruijsse, H. D.,Brandsma, L.
, p. 113 - 114 (2007/10/02)
Acetylenes HCC-CH2-R (R = H, alkyl) have been converted with good yields into their derivatives HCC-CH(E)-R (E = -CH2CHR'OH, -CH2Ph, -SiMe3) by reaction of the dilithio compound LiCC-CH(Li)-R with epoxides OC2H3-R' (R' = H, Ph), benzyl chloride and trimethylchlorosilane (TMSCl), respectively.
