72308-62-4Relevant academic research and scientific papers
Molecular Sieve-assisted Oxidations: New Methods for Carbohydrate Derivative Oxidations
Herscovici, Jean,Antonakis, Kostas
, p. 561 - 562 (1980)
Molecular sieves catalyse pyridinium chlorochromate and pyridinium dichromate oxidation and so give rise to an efficient synthesis of ketonucleosides and ketosugars at room temperature.
New Oxidative Systems for Alcohols: Molecular Sieves with Chromium (VI) Reagents
Herscovici, Jean,Egron, Marie-Jose,Antonakis, Kostas
, p. 1967 - 1974 (2007/10/02)
The oxidation of various kinds of alcohols, including carbohydrates and nucleosides, by molecular sieve-pyridinium chlorochromate and molecular sieve-pyridinium dichromate has been investigated.The catalytic properties of molecular sieves have been investigated using kinetic, stereochemical, and isotope-labelling experiments.It is postulated that specific sites on the sieves favour hydride-ion transfer.
