7239-25-0

Usage

Tert-butyl group

A saturated hydrocarbon group with a tertiary carbon atom, providing steric hindrance and stability.

Difluoro(phenyl)silyl group

A phenyl group with two fluorine atoms attached, connected to a silicon atom, which can enhance the compound's reactivity and stability.

Fluoro-phenyl group

A phenyl group with one fluorine atom attached, which can influence the compound's electronic properties and reactivity.

Trimethylphenyl group

A phenyl group with three methyl groups attached (2,4,6 positions), which can affect the compound's solubility and stability.

Amine functional group

A nitrogen atom bonded to two organic groups, which can participate in hydrogen bonding and various chemical reactions, such as nucleophilic substitution.

Silane functional group

A silicon atom bonded to one or more hydrogen atoms, which can provide unique reactivity and stability in chemical reactions.

Complex structure

The combination of various functional groups results in a complex molecule with potential unique properties and applications in organic synthesis, medicinal chemistry, and materials science.

Upstream product

• 7207-01-4 4-Acetoxy-2-benzyl-1-phenyl-but-2-en 
• 7206-98-6 (4-bromo-2-benzylbut-2-enyl)benzene 
• 102-04-5 1,3-Diphenylpropanone 
• 198547-74-9 ethyl 3-benzyl-4-phenylbut-2-enoate 

Relevant academic research and scientific papers

Visible-Light Mediated Hydrosilylative and Hydrophosphorylative Cyclizations of Enynes and Dienes

Described herein is a visible-light mediated intermolecular radical cyclization approach to access heterocycles. Heteroatom radicals, such as silicon and phosphorus atom radicals, were generated via direct hydrogen atom abstraction by the photoexcited catalyst species with hydro-silanes and phosphine oxides. The radical addition/cyclization/HAT (hydrogen atom transfer) reaction sequences of 1,6-enynes and 1,6-dienes were highly efficient delivering the desired heterocycles in good yields.

The Isomerization of Allylrhodium Intermediates in the Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines

Allylrhodium species generated from potassium allyltrifluoroborates can undergo isomerization by 1,4-rhodium(I) migration to give more complex isomers, which then react with cyclic imines to provide products with up to three new stereochemical elements. High enantioselectivities are obtained using chiral diene-rhodium complexes. Rhodium dance: Allylrhodium species generated from potassium allyltrifluoroborates can undergo isomerization by a 1,4-rhodium(I) migration to give more complex isomers, which then react with cyclic imines to provide products with up to three new stereochemical elements. High enantioselectivities are obtained with chiral diene-rhodium complexes.