72414-52-9

Upstream product

• 17685-52-8 triiron dodecarbonyl 
• 100-47-0 benzonitrile 

Downstream Products

• 17685-52-8 triiron dodecarbonyl 
• 63104-17-6 Fe₃*9CO*3P(OCH₃)3 = [Fe₃(CO)9(P(OCH₃)3)3] 
• 63104-16-5 Fe₃*10CO*2P(OCH₃)3 = [Fe₃(CO)10(P(OCH₃)3)2] 
• 168842-38-4 Fe3(CO)8(P(OMe)3)(μ3-η2-NCPh) 
• 168557-59-3 {Fe4(CO)12(μ4-PhCN)} 

Relevant academic research and scientific papers

Benzonitrile as a 6-Electron Donor Ligand: The Clusters Fe3(CO)9(μ3(η2)-NCC6H5) and Fe4(CO)12(μ4(η2)-NCC6H5)

The reaction of Fe3(CO)12 with benzonitrile in the presence of hydrogen leads to the benzonitrile complexes Fe3(CO)9(μ3(η2)-NCC6H5) (1a) and Fe4(CO)12(μ4(η2)-NCC6H5) (2).Their structures were determined crystallographically.The benzonitrile ligand is coordinated to the iron atoms formally via one ?-bond and two ?-bonds in 1a, and via three ?-bonds and one ?-bond in 2.