72443-58-4

Upstream product

• 72443-54-0 Benzyldimethyl<(methyldiphenylsilyl)methyl>ammonium bromide 
• 2083-91-2 N,N-Dimethyltrimethylsilylamine 
• 3839-30-3 methyldiphenylsilyllithium 
• 529-20-4 2-methylphenyl aldehyde 

Relevant academic research and scientific papers

Aminosilylation of aldehydes mediated by lithium perchlorate: Novel method for synthesis of α-silylamines

α-Silylated N,N-dialkylamines 7a-k were easily synthesized in good to excellent yields from aldehydes 1, (trimethylsilyl)dialkylamines 2, and phenyldimethylsilyllithium 4, diphenylmethylsilyllithium 5, or triphenylsilyllithium 6, in concentrated ethereal

Ylide Reactions of Benzyldimethylammonium Halides

Deprotonation of benzyldimethylammonium halides (10) with sodium amide or n-butyllithium afforded silylated ylide intermediates 11, which were rearranged into N,N-dimethyl-2-benzylamines (13) accompanied by the formation of Sommelet-Hauser and Stevens rearrangement products (12 and 22).The ylide formation by the cleavage of carbon-silicon bonds also is discussed in the reaction of 10 with sodium amide and lithium aluminum hydride.