725268-46-2

Upstream product

• 725268-58-6 Toluene-4-sulfonic acid 2-((1S,3R,4R)-3,4-bis-benzyloxy-cyclohexyl)-ethyl ester 
• 725268-44-0 3-((1S,3R,4R)-3,4-Bis-benzyloxy-cyclohexyl)-propionic acid 
• 725268-59-7 3-((1R,3R,4R)-3,4-Bis-benzyloxy-cyclohexyl)-propionitrile 
• 725268-43-9 2-((1S,3R,4R)-3,4-Bis-benzyloxy-cyclohexyl)-ethanol 
• 74-88-4 methyl iodide 
• 725268-45-1 (R)-4-Benzyl-3-[3-((1S,3R,4R)-3,4-bis-benzyloxy-cyclohexyl)-propionyl]-oxazolidin-2-one 

Downstream Products

• 725268-50-8 (3S,4R)-5-((1S,3R,4R)-3,4-Bis-benzyloxy-cyclohexyl)-4-methyl-pent-1-en-3-ol 
• 725268-48-4 (E)-(R)-5-((1S,3R,4R)-3,4-Bis-benzyloxy-cyclohexyl)-4-methyl-pent-2-en-1-ol 
• 725268-49-5 {(2R,3R)-3-[(R)-2-((1S,3R,4R)-3,4-Bis-benzyloxy-cyclohexyl)-1-methyl-ethyl]-oxiranyl}-methanol 
• 725268-61-1 (E)-(R)-5-((1S,3R,4R)-3,4-Bis-benzyloxy-cyclohexyl)-4-methyl-pent-2-enoic acid ethyl ester 
• 725268-51-9 (2R,3R)-4-((1S,3R,4R)-3,4-Bis-benzyloxy-cyclohexyl)-2-(tert-butyl-dimethyl-silanyloxy)-3-methyl-butan-1-ol 
• 725268-33-7 [(1R,2R)-3-((1S,3R,4R)-3,4-Bis-benzyloxy-cyclohexyl)-1-iodomethyl-2-methyl-propoxy]-tert-butyl-dimethyl-silane 
• 725268-55-3 [(E)-(1S,4R)-3-Benzenesulfonyl-1-[(R)-2-((1S,3R,4R)-3,4-bis-benzyloxy-cyclohexyl)-1-methyl-ethyl]-9-(4-methoxy-benzyloxy)-4-methyl-non-5-enyloxy]-tert-butyl-dimethyl-silane 
• 725268-47-3 (R)-3-((1S,3R,4R)-3,4-Bis-benzyloxy-cyclohexyl)-2-methyl-propan-1-ol 

Relevant academic research and scientific papers

Synthetic studies on antascomicin A: Construction of the C18-C34 fragment

Stereoselective synthesis of the C18-C34 fragment of antascomicin A is described. Construction of the C27-C34 carbocycle moiety was achieved via catalytic Ferrier carbocylization and Johnson-Claisen rearrangement, which was converted to iodide 2 by use of