72530-35-9Relevant academic research and scientific papers
Tuning the reactivity of oxygen/sulfur by acidity of the catalyst in Prins cyclization: Oxa-versus thia-selectivity
Subba Reddy,Venkateswarlu,Borkar, Prashant,Yadav,Sridhar,Gree, Rene
, p. 2716 - 2722 (2014/04/17)
An unprecedented oxa- versus thia-selectivity has been observed in Prins cyclization of 6-mercaptohex-3-en-1-ol with aldehydes. In the presence of a stoichiometric amount of strong Lewis or Bronsted acids, the reaction provides the hexahydro-2H-thieno[3,2
Synthesis of the Sesquiterpene (+/-)-Lemnal-5a-en-2-one
Dischmann, Michael,Ernst, Ludger,Wolf, Herbert
, p. 727 - 738 (2007/10/02)
SnCl4-catalysed cyclization of the carboxylic acid 4 stereoselectively gives the tricyclus 5.This cyclization is the key reaction in the synthesis of lemnal-5a-en-2-one .As a model compound the carboxylic acid 2 was cyclized to yield 3. 2 and 4 w
Synthesis of ω-Tritiated and ω-Fluorinated Analogues of the Trail Pheromone of Subterranean Termites
Carvalho, Joan F.,Prestwich, Glenn D.
, p. 1251 - 1258 (2007/10/02)
A series of unsaturated ω-fluoro alcohols have been prepared stereoselectively.These simple compounds are structural analogues of the trail pheromone of termites in the genus Reticulitermes.The toxicity of these ω-fluoro alcohols to R. flavipes is maximal for the C12 alcohols, and the attractiveness of these C12 analogues increases in the order saturated alkanol -12-fluoro alcohols and a -nonfluorinated analogue were prepared to examine the catabolism of the pheromone analogues.
