72535-87-6Relevant academic research and scientific papers
Evidence for a Novel Mechanism of the 1,2-Bond Shift Rearrangements catalysed by Coenzyme-B12
Hamilton, Robert,Mitchell, Thomas R. B.,McIlgorm, Edward A.,Rooney, John J.,McKervey, M. Anthony
, p. 686 - 688 (2007/10/02)
The olefinic products arising from the oxidative addition at ambient temperatures of 2,2,6,6-tetramethylcyclohex-1-yl toluene-p-sulphonate to (PPh3)2CoBr2, (PPh3)2NiBr2, and hydroxo-cobalamin, all reduced with sodium borohydride, or to (Me)2CuLi, provide firm evidence for a novel mechanism of the 1,2-bond shift rearrangements catalysed by vitamin B12 coenzyme.
