72576-49-9Relevant academic research and scientific papers
A CATIONIC YLIDE COMPLEX OF PLATINUM(II): ITS STRUCTURE AND FORMATION FROM A CHLOROMETHYL-PLATINUM COMPLEX
Engelter, Carola,Moss, John R.,Niven, Margaret L.,Nassimbeni, Luigi R.,Reid, Gordon
, p. C78 - C80 (1982)
The reactions of cis- or trans- with triphenylphosphine give the ylide complex cis-I.The reactions involve a novel migration of Cl from a CH2 group to Pt.The structure of the cationic ylide complex has been determi
Haloalkyl Complexes of the Transition Metals IV. The Formation of a Cationic Ylide Complex of Platinum(II) from a Chloromethylplatinum(II) Complex and The Crystal Structures of cis-I (X= Cl or I)
Engelter, Carola,Moss, John R.,Nassimbeni, Luigi R.,Niven, Margaret L.,Reid, Gordon,Spiers, John C.
, p. 255 - 268 (2007/10/02)
The reactions of Pt(PPh3)4 and Pt(C2H4)(PPh3)2 with CH2ClI have been investigated.The product of the reaction of Pt(PPh3)4 with CH2ClI is the cationic ylide complex cis-, whereas the reaction of Pt(C2H4)(PPh3)2 gives the oxidative
