7261-23-6Relevant academic research and scientific papers
Sterically Hindered Free Radicals. 18. Stabilization of Free Radicals by Substituents As Studied by Using Triphenylmethyls
Neumann, Wilhelm P.,Penenory, Alicia,Stewen, Ulrich,Lehnig, Manfred
, p. 5845 - 5851 (2007/10/02)
The relative stabilization of 10 4-mono- and 24 4,4'-disubstituted triphenylmethyl radicals 1 has been measured by recording the degree of dissociation of the corresponding quinonoid dimers 2 by means of ESR.The following substituents or combinations of t
Sterically Hindered Free Radicals, XV The First Unsymmetrical Dimer from Two Different Stable Radicals: 3-(tert-Butylphenylmethylene)-6-(triphenylmethyl)-1,4-cyclohexadiene from tert-Butyldiphenylmethyl and Triphenylmethyl
Neumann, Wilhelm P.,Stapel, Ralf
, p. 2006 - 2012 (2007/10/02)
The quinonoid title compound 6 is formed in an equilibrium to 95percent and can be isolated, when the two title radicals 1 and 3 are generated in solution.The reason for this is the sterically less strained position of the bulky tBu group at the sp2
