72643-70-0

Basic information

• Product Name: 2-Propenoic acid, 3,3'-(2,5-furandiyl)bis-, dimethyl ester, (2E,2'E)-
• CAS NO: 72643-70-0
• Molecular Formula: C12H12O5
• Molecular Weight: 236.224
• Mol File: 72643-70-0.mol

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3,3'-(2,5-furandiyl)bis-, dimethyl ester, (2E,2'E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3,3'-(2,5-furandiyl)bis-, dimethyl ester, (2E,2'E)-(72643-70-0)
• EPA Substance Registry System: 2-Propenoic acid, 3,3'-(2,5-furandiyl)bis-, dimethyl ester, (2E,2'E)-(72643-70-0)

Safety Data

• Hazardous Substances Data: 72643-70-0(Hazardous Substances Data)

Upstream product

• 110-00-9 furan 
• 292638-85-8 acrylic acid methyl ester 

Downstream Products

• 129012-09-5 5-[5-((Z)-2-Methoxycarbonyl-vinyl)-furan-2-yl]-3-phenyl-4,5-dihydro-isoxazole-4-carboxylic acid methyl ester 
• 129012-08-4 C₂₆H₂₂N₂O₇ 
• 4412-78-6 3-[5-(3-hydroxy-propyl)-furan-2-yl]-propan-1-ol 

Relevant articles and documents

Palladium-Catalyzed Alkenylation of Aromatic Heterocycles with Olefins. Synthesis of Functionalized Aromatic Heterocycles

Aromatic heterocycles such as furan, thiophene, benzofuran, benzothiophene, and N-acetylindole undergo facile palladium-assisted alkenylation with various olefins to produce mono- and/or dialkenylated heterocycles in high yield.With furan and thiophene, the reaction is regioselective, giving products substituted at the 2-position of the heterocycles, and is also stereoselective, giving E products when the substituent on the olefin is bulky.The reactions of benzofuran and N-acetylindole with olefins give cyclization products such as dibenzofuran and carbazole derivatives together with alkenylated products.The mechanistic implications with respect to these alkenylations are discussed.