72681-02-8

Basic information

• Product Name: (Z)-3-Methyl-5-phenyl-2-penten-1-ol
• Synonyms: (Z)-3-Methyl-5-phenyl-2-penten-1-ol
• CAS NO: 72681-02-8
• Molecular Weight: 176.258
• Mol File: 72681-02-8.mol

Chemical Properties

• CAS DataBase Reference: (Z)-3-Methyl-5-phenyl-2-penten-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3-Methyl-5-phenyl-2-penten-1-ol(72681-02-8)
• EPA Substance Registry System: (Z)-3-Methyl-5-phenyl-2-penten-1-ol(72681-02-8)

Safety Data

• Hazardous Substances Data: 72681-02-8(Hazardous Substances Data)

Upstream product

• 35761-83-2 3-iodo-but-2-ene-1-ol 
• 1259929-98-0 tert-butyl (Z)-3-methyl-5-phenyl-2-pentenoate 
• 70319-43-6 (Z)-3-methyl-5-phenyl-2-pentenoic acid ethyl ester 

Downstream Products

• 55066-48-3 3-methyl-5-phenylpentan-1-ol 
• 72681-08-4 (E)-3-methyl-5-phenyl-pent-2-en-1-ol 
• 75553-29-6 3-Methyl-5-phenyl-3-penten-1-ol 
• 102222-85-5 3-methyl-5-phenylpent-2-enyl methyl ether 
• 90866-30-1 (R)-(+)-3-methyl-5-phenylpentan-1-ol 
• 41927-33-7 (S)-(-)-3-methyl-5-phenylpentan-1-ol 
• 942416-33-3 (R)-(+)-3-methyl-5-phenylpentanaldehyde 
• 942416-34-4 (S)-(-)-3-methyl-5-phenylpentanaldehyde 
• 1431460-73-9 diethyl (Z)-3-methyl-5-phenyl-2-pentenyl phosphate 
• 1270304-89-6 dimethyl[(1S)-1-methyl-1-(2-phenylethyl)prop-2-en-1-yl]phenylsilane 
• 1270304-95-4 dimethyl[(1R)-1-methyl-1-(2-phenylethyl)prop-2-en-1-yl]phenylsilane 
• 1431461-17-4 C₂₀H₂₆Si 

Relevant articles and documents

Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides

A highly regio- and enantioselective copper-catalyzed three-component coupling of isocyanides, hydrosilanes, and γ,γ-disubstituted allylic phosphates/chlorides to afford chiral α-quaternary formimides was enabled by the combined use of our original chiral

Enantioselective synthesis of α-tri- and α-tetrasubstituted allylsilanes by copper-catalyzed asymmetric allylic substitution of allyl phosphates with silylboronates

A copper/N-heterocyclic carbene-catalyzed asymmetric allylic substitution of allyl phosphates with a silylboronate has been developed to give highly enantioenriched allylsilanes. High regioselectivity has been achieved by employing NaOH as the base, and this catalyst system is effective for both γ-mono- and disubstituted allyl phosphates.

HIGHLY STEREOSELECTIVE AND GENERAL SYNTHESIS OF (Z)-3-METHYL-2-ALKEN-1-OLS VIA PALLADIUM-CATALYZED CROSS COUPLING OF (Z)-3-IODO-2-BUTEN-1-OL WITH ORGANOZINCS AND OTHER ORGANOMETALS

The reaction of Zn-protected (Z)-3-iodo-2-buten-1-ol with organozincs in the presence of 1-5 mol percent of a Pd complex, e.g., Pd(PPh3)4 or Cl2Pd(PPh3)2 and n-BuLi (2 equiv), in DMF provides a highly stereoselective (>/= 96 percent), general, and high-yi