72681-90-4

Basic information

• Product Name: p-chlorobenzyl octyl ether
• Synonyms: p-chlorobenzyl octyl ether
• CAS NO: 72681-90-4
• Molecular Weight: 254.8
• Mol File: 72681-90-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: p-chlorobenzyl octyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: p-chlorobenzyl octyl ether(72681-90-4)
• EPA Substance Registry System: p-chlorobenzyl octyl ether(72681-90-4)

Safety Data

• Hazardous Substances Data: 72681-90-4(Hazardous Substances Data)

Upstream product

• 111-87-5 octanol 
• 78358-09-5 40chlorobenzyl methanesulfonate 
• 622-95-7 4-chlorobenzyl bromide 
• 14246-16-3 trimethyl(oct-1-yloxy)silane 
• 104-88-1 4-chlorobenzaldehyde 

Downstream Products

• 30203-87-3 1-chloro-4-(4-methylbenzyl)benzene 
• 91410-28-5 1-chloro-4-(3-methylbenzyl)benzene 
• 55676-88-5 1-chloro-4-(2-methylbenzyl)benzene 
• 124-07-2 Octanoic acid 

Relevant articles and documents

Benzylation of alcoholic hydroxyl groups with benzyl mesylate by using a catalytic amount of lithium tetrakis(pentafluorophenyl)borate in the coexistence of lithium triflate and magnesium oxide

Several alcohols possessing alkali-labile substituents such as halogen, ester and ketone were effectively benzylated with benzyl mesylate by using a catalytic amount of lithium tetrakis(pentafluorophenyl)borate [LiB(C6F5)4] in the coexistence of lithium triflate (LiOTf) and magnesium oxide (MgO) to afford the corresponding benzyl ethers in good to excellent yields.

Cu(OTf)2-catalyzed Et3SiH-reductive etherification of various carbonyl compounds with trimethylsilyl ethers

A triethylsilane-reductive etherification of the trimethylsilyl ethers with a variety of carbonyl compounds in good yields at room temperature employing 0.5 mol% Cu(OTf)2 as an extremely efficient catalyst is described here.