727381-45-5

Basic information

• Product Name: Pd(C₆H₅CH₂NCH₃CH₂)2(OC₁₀H₅CH₃)2
• CAS NO: 727381-45-5
• Molecular Weight: 687.19
• Mol File: 727381-45-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pd(C₆H₅CH₂NCH₃CH₂)2(OC₁₀H₅CH₃)2(CAS DataBase Reference)
• NIST Chemistry Reference: Pd(C₆H₅CH₂NCH₃CH₂)2(OC₁₀H₅CH₃)2(727381-45-5)
• EPA Substance Registry System: Pd(C₆H₅CH₂NCH₃CH₂)2(OC₁₀H₅CH₃)2(727381-45-5)

Safety Data

• Hazardous Substances Data: 727381-45-5(Hazardous Substances Data)

Upstream product

• 55515-98-5 (R)-3,3'-dimethyl-1,1'-bi-2-naphthol 
• 102-18-1 N,N’-dimethyl-N,N’-dibenzylethylenediamine 
• 3375-31-3 palladium diacetate 

Downstream Products

• 50723-62-1 PdCl₂(C₆H₅CH₂NCH₃CH₂)2 

Relevant articles and documents

Persistent N-chirality as the only Source of asymmetry in nonracemic N 2PdCl2 complexes

The combination of prochiral 1,2-diamines, Pd(OAc)2, and (R)-K2-3,3′-Me2BINOL leads to enantio- and diastereopure N2Pd(3,3′-Me2BINOL) complexes. HCl removes the Me2BINOL resolving ligand and provides a family of enantiopure N2PdCl2 complexes whose only stereochemistry resides on the stereogenic nitrogen centers. In effect, nitrogen inversion (>105 s-1) is halted by metal coordination and utilized to generate enantiopure complexes. When the diamine substituents are relatively small, the N-chirality is stable; however, large substituents accelerate N-dissociation processes and concomitant racemization. Enantiopure N 2Pd2+-Lewis acid catalysts can be generated for the Diels-Alder reaction, and although enantioselectivities are low (a degradation of the catalyst's chirality.