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trans-3-(2-Chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl-cyclopropanecarboxylic Acid is a complex organic compound characterized by its unique molecular structure, featuring a cyclopropane ring with a carboxylic acid group and a trifluoromethyl-substituted propenyl group. trans-3-(2-Chloro-3,3,3-trifluoro-1-propenyl)-2,2-diMethyl-cyclopropanecarboxylic Acid is known for its reactivity and potential applications in the synthesis of various chemical products.
Used in Chemical Synthesis Industry:
trans-3-(2-Chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl-cyclopropanecarboxylic Acid is used as a reagent for the synthesis of indanyl insecticides. Its unique structure allows it to act as a key intermediate in the production of these insecticides, which are designed to control and manage various types of pests in agricultural and other settings. trans-3-(2-Chloro-3,3,3-trifluoro-1-propenyl)-2,2-diMethyl-cyclopropanecarboxylic Acid's reactivity and stability make it a valuable component in the development of effective and environmentally friendly pest control solutions.

72748-68-6

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72748-68-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 72748-68-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,2,7,4 and 8 respectively; the second part has 2 digits, 6 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 72748-68:
(7*7)+(6*2)+(5*7)+(4*4)+(3*8)+(2*6)+(1*8)=156
156 % 10 = 6
So 72748-68-6 is a valid CAS Registry Number.
InChI:InChI=1/C9H10ClF3O2/c1-8(2)4(6(8)7(14)15)3-5(10)9(11,12)13/h3-4,6H,1-2H3,(H,14,15)/b5-3-/t4-,6+/m1/s1

72748-68-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name (1R,3S)-3-[(Z)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-dimethylcyclopropane-1-carboxylic acid

1.2 Other means of identification

Product number -
Other names (E)-(1RS,3RS)-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
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More Details:72748-68-6 SDS

72748-68-6Relevant academic research and scientific papers

PRACTICAL AND STEREOCONTROLLED SYNTHESES OF BOTH (1R*,3S*)- AND (1R*,3R*)-3-(2-CHLORO-3,3,3-TRIFLUORO-1-PROPENYL)-2,2-DIMETHYLCYCLOPROPANECARBOXYLATES

Fujita, Makoto,Hiyama, Tamejiro,Kondo, Kiyosi

, p. 2139 - 2142 (2007/10/02)

The title compounds of (1R*,3S*) configuration were prepared from 3-formyl-2,2-dimethylcyclopropanecarboxylate by addition of CF3CCl2ZnCl, acetylation, and reductive β-elimination with zinc, whereas the (1R*,3R*) isomer was derived from Me2C=CHCH(OH)CCl2CF3 by diazoacetylation, Cu(II) catalyzed intramolecular cyclization, and the zinc reduction.

Synthesis and X-Ray Crystal Structure of a New Potent Pyrethroid Acid, (+/-)-cis-3--2,2-dimethylcyclopropanecarboxylic Acid

Engel, John F.,McPhail, Andrew T.,Miller, Richard W.

, p. 1737 - 1740 (2007/10/02)

Single-crystal X-ray analysis of the title compound has established its structure and molecular geometry.Crystals are monoclinic, space group P21/c, with a = 9.487(4), b = 8.009(4), c = 16.214(6) Angstroem, β = 119.91(1) deg, Z = 4.The structure was solved by direct methods and refined by full-matrix least-squares calculations to R 0.056 over 1242 reflections measured by diffractometer.The crystals contain centrosymmetric hydrogen-bonded dimers (O...O 2.65 Angstroem) in which the carboxy and vinyl substituents are in a 'bisecting' orientation, and the C=O group and one of hydrogen atoms on each methyl group point over the cyclopropane ring.The bond lengths in the ring reflect the substitution pattern.

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