72802-79-0Relevant academic research and scientific papers
Propynal equivalents and diazopropyne: Synthesis of all mono-13C isotopomers
Seburg, Randal A.,Hodges, Jonathan A.,McMahon, Robert J.
experimental part, p. 1626 - 1643 (2009/10/17)
Mechanistic and spectroscopic investigations of reactive C 3H2 hydrocarbons necessitated the preparation of diazopropyne isotopomers bearing mono-13C substitution at each of the three unique positions. The diazo compounds and their tosylhydrazone precursors were prepared from the mono-13C isotopomers of propynal (in the form of either the aldehyde or the diethyl acetal). The introduction of 13C-labeling at either alkyne position in propynal utilized the Corey - Fuchs procedure for chain homologation.
