72805-00-6Relevant academic research and scientific papers
Improved Reagent for Electrophilic Amination of Stabilized Carbanions
Smulik, Jason A.,Vedejs, Edwin
, p. 4187 - 4190 (2007/10/03)
(Equation presented) Enolate amination using O-di(p-methoxyphenyl) phosphinylhydroxylamine 2 is reported. Reagent 2 reacts efficiently with stabilized sodium or potassium enolates derived from malonates, phenylacetates, and phenylacetonitriles and is sufficiently soluble for use in solution at -78°C.
O-(Diphenylphosphinyl)hydroxylamine: Preparation and Some Characteristic Chemical Reactions
Harger, Martin J. P.
, p. 3284 - 3288 (2007/10/02)
Hydroxylamine reacts with diphenylphosphinic chloride (1) in benzene (or aqueous dioxan) to give O-(diphenylphosphinyl)hydroxylamine (3) and not the N-phosphinyl compound (2) as was previously thought.Di-p-tolyl-, bis-p-methoxyphenyl-, and phenyl-p-methox
