72844-95-2Relevant academic research and scientific papers
The reactions of N-substituted 2-(dimethylallyl)aniline compounds with phenylselanyl halides
Cooper, Matthew A.,Francis, Craig L.,Holman, Jeffrey W.,Kasum, Bruno,Taverner, Thomas,Tiekink, Edward R.T.,Ward, A. David
, p. 123 - 129 (2007/10/03)
Cyclization of the carbamate of 2-(dimethylallyl)aniline with phenylselanyl chloride (benzeneselenenyl chloride) gave a 1 : 1 mixture of a dihydroindole and a tetrahydroquinoline. With phenylselanyl bromide only the dihydroindole was obtained. Addition of
Cyclofunctionalization of Olefinic Urethanes Using Benzeneselenenyl Chloride in the Presence of Silica Gel: A General Route to Nitrogen Heterocycles
Clive, D. L. J.,Farina, Vittorio,Singh, Alok,Wong, Chi Kwong,Kiel, William, A.,Menchen, Steven M.
, p. 2120 - 2126 (2007/10/02)
Ethyl urethanes derived from Δ4 or Δ5 olefinic amines undergo cyclofunctionalization to afford pyrrolidines and piperidines, respectively, when treated with benzeneselenenyl chloride.The reaction is an efficient one when carried out in the presence of silica gel, yields generally being above 80percent for the examples studied.
