72897-05-3

Upstream product

• 50-00-0 formaldehyd 
• 62-53-3 aniline 
• 3127-08-0 bis(hydroxymethyl)phenylphosphine 
• 72936-83-5 bis(phenylaminomethyl)phenylphosphine 

Downstream Products

• 75593-74-7 1,3,5,7-tetraphenyl-1,5-diaza-3,7-diphosphacyclooctane 
• 74607-62-8 5-phenyl-5-oxo-1,3-diphenyl-1,3,5-diazaphosphorinane 
• 174321-06-3 (1,3,5-triphenyl-1,3,5-diazaphosphorinane)pentacarbonyltungsten 
• 145957-04-6 cis-{bis(1,3,5-triphenyl-1,3,5-diazaphosphorinane)}dichloropalladium(II) 
• 134097-08-8 {C₃H₆N₂P(C₆H₅)3}2NiCl₂ 
• 134097-07-7 {C₃H₆N₂P(C₆H₅)3}2CoCl₂ 
• 181963-80-4 {C₃H₆N₂P(C₆H₅)3}2PtCl₂ 
• 141780-57-6 (1,3,5-triphenyl-1,3,5-diazaphosphorinane)pentacarbonylmolybdenum(O) 

Relevant academic research and scientific papers

SYNTHESIS AND PROPERTIES OF TRIETHYLAMMONIUM 2,2,5-TRIPHENYL-1,3,2,5-DIOXABORATAPHOSPHORINANE

The reaction of bis(hydroxymethyl)phenylphosphine with isobutyl diphenylborate in the presence of triethylamine leads to the formation of triethylammonium 2,2,5-triphenyl-1,3,2,5-dioxaborataphosphorinane (1).The reaction of compound 1 with electrophilic reagents (O, S, Se, CH2O, RHal) leds to quaternization of the phosphorus atom, giving the corresponding phosphine oxides, sulfides, and selenides and P,B-containing betaines.In the reactions of compound 1 with amines aminomethylphosphines of the diazaphosphorinane and diazadiphosphacyclooctane series are formed.Ammonium 1,3,2,5-dioxaborataphosphorinanes dissociate in solution and enter into ion exchange with phosphonium iodides, leading to phosphonium 1,3,2,5-dioxaborataphosphorinanes.The latter, in the case of the aminomethylphosphonium cation, undergo intramolecular rearrangement with the formation of P,B-containing betaines and aminomethylphosphines. Keywords: Triethylammonium 2,2,5-triphenyl-1,3,2,5-dioxaborataphosphorinane, oxide, sulfide, aminomethylphosphine, ion exchange, triphenylmethylphosphonium 1,3,2,5-dioxaborataphosphorinane.

1.2-DIAZA-4-PHOSPHA-CYCLOPENTANE - 1.5-DIAZA-3.7-DIPHOSPHABICYCLO-OCTANE N.N'--N.N'-DIMETHYLHYDRAZINE 1.3-DIAZA-5-PHOSPHA-CYCLOHEXANE

N.N'-Dialkylhydrazines and hydrazine itself react with hydroxymethylphosphines to give the title compounds, bis(anilinomethylen)-phosphines form the cyclohexane-derivatives with formaldehyde.