729593-90-2

Upstream product

• 729593-88-8 (+)-(3S,4S,5R,6S)-6-phenyl-5-(p-tolylsulfonyl)-tetrahydro-2H-pyran-3,4-diol 
• 729593-95-7 (-)-(S)-2-(Z)-4-(Z)-5-phenyl-4-(p-tolylsulfinyl)penta-2,4-dien-1-ol 
• 729593-99-1 (-)-(2S,3R,R_S)-2-phenyl-3-(p-tolylsulfinyl)-3,6-dihydro-2H-pyran 

Relevant academic research and scientific papers

Base-induced enantioselective synthesis of sulfinyl dihydropyrans

2-Sulfinyl dienols undergo an efficient base-promoted cyclization to produce sulfinyl dihydropyrans with creation of two asymmetric centers. The configurational stability of the allylic sulfoxide in most cases is noteworthy. Simple manipulations lead to a

Sulfoxide-directed enantioselective synthesis of functionalized dihydropyrans

The highly selective base-promoted cyclization of enantiopure sulfinyl dienols affords allylic sulfinyl dihydropyrans.