729596-19-4Relevant academic research and scientific papers
Regioselective epoxide opening of epoxyamides derived from d-glucose. Cyclization approaches to azepanes
O?a, Noe,Romero-Carrasco, Antonio,Pino-González, M. Soledad
, p. 156 - 163 (2013/04/10)
Epoxyamides obtained from d-glucose have been evaluated as tools to obtain polyhydroxyazepanes. The stereoselectivity in formation of the epoxyamides was proven to be dependent of the protecting group. The conversion of epoxyamides into epoxyalcohols was
Synthesis of azepane and nojirimycin iminosugars: the Sharpless asymmetric epoxidation of d-glucose-derived allyl alcohol and highly regioselective epoxide ring opening using sodium azide
Jadhav, Vrushali H.,Bande, Omprakash P.,Puranik, Vedavati G.,Dhavale, Dilip D.
experimental part, p. 163 - 170 (2010/05/02)
The Sharpless asymmetric epoxidation of d-glucose-derived allyl alcohol 4 afforded α- and β-epoxides 5a and 5b in high stereoselectivity. The epoxide ring opening in 5a/5b was studied with different nucleophilic azido reagents, under various reaction cond
Asymmetric dihydroxylation of D-glucose derived α,β-unsaturated ester: Synthesis of azepane and nojirimycin analogues
Dhavale, Dilip D.,Markad, Shankar D.,Karanjule, Narayan S.,PrakashaReddy
, p. 4760 - 4766 (2007/10/03)
The asymmetric dihydroxylation of a D-glucose derived α,β- unsaturated ester 3 afforded syn vicinal diols in good to high diastereoselectivity. The conversion of these vicinal diols to the corresponding cyclic sulfate, regio-, stereoselective nucleophilic
