729596-23-0Relevant academic research and scientific papers
Synthesis of azepane and nojirimycin iminosugars: the Sharpless asymmetric epoxidation of d-glucose-derived allyl alcohol and highly regioselective epoxide ring opening using sodium azide
Jadhav, Vrushali H.,Bande, Omprakash P.,Puranik, Vedavati G.,Dhavale, Dilip D.
experimental part, p. 163 - 170 (2010/05/02)
The Sharpless asymmetric epoxidation of d-glucose-derived allyl alcohol 4 afforded α- and β-epoxides 5a and 5b in high stereoselectivity. The epoxide ring opening in 5a/5b was studied with different nucleophilic azido reagents, under various reaction cond
Asymmetric dihydroxylation of D-glucose derived α,β-unsaturated ester: Synthesis of azepane and nojirimycin analogues
Dhavale, Dilip D.,Markad, Shankar D.,Karanjule, Narayan S.,PrakashaReddy
, p. 4760 - 4766 (2007/10/03)
The asymmetric dihydroxylation of a D-glucose derived α,β- unsaturated ester 3 afforded syn vicinal diols in good to high diastereoselectivity. The conversion of these vicinal diols to the corresponding cyclic sulfate, regio-, stereoselective nucleophilic
