72991-62-9Relevant academic research and scientific papers
A highly efficient titanium catalyst for the synthesis of ultrahigh-molecular-weight polyethylene (UHMWPE)
Haas, Isabelle,Huebner, Christian,Kretschmer, Winfried P.,Kempe, Rhett
, p. 9132 - 9136 (2013/07/26)
Long chain running: The polymerization performance of guanidinato titanium(IV) olefin catalysts is tuned by monodentate ancillary ligands. Polymerization activities of up to 8800 kgPE molcat. -1 h-1 bar-1/
Effect of ligand substituents in olefin polymerisation by half-sandwich titanium complexes containing monoanionic iminoimidazolidide ligands-MAO catalyst systems
Nomura, Kotohiro,Fukuda, Hiroya,Katao, Shohei,Fujiki, Michiya,Kim, Hyun Joon,Kim, Dong-Hyun,Zhang, Shu
scheme or table, p. 7842 - 7849 (2011/09/20)
Various half-sandwich titanium complexes containing iminoimidazolidide ligands, CpTiCl2[1,3-R2(CH2N)2CN] (1a-d) [R = Ph (a), 2,6-Me2C6H3 (b), cyclohexyl (c), tBu (d)], have been employed as the catalyst precursors for ethylene polymerisation, syndiospecific styrene polymerisation, and copolymerisation of ethylene with 1-hexene in the presence of MAO cocatalyst; 1d showed the highest catalytic activity for ethylene polymerisation whereas 1b showed the highest activity for syndiospecific styrene polymerisation.
1,3-Diaryl-2-imino-imidazolidines and compositions thereof
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, (2008/06/13)
The invention relates to new compounds of the general formula (I), STR1 wherein R1 and R5 each represent a phenyl group, optionally substituted, R2 stands for hydrogen, formyl group, carboxy group, lower alkoxycarbonyl gro
