7301-94-2Relevant academic research and scientific papers
Spontaneous dehydrogenation of 2-hydrazinoethyl- and 4-hydrazinobut-2- enylphosphonium salts
Ovakimyan,Gasparyan,Movsisyan,Grigoryan
, p. 2338 - 2343 (2013/10/01)
2-Hydrazinoethyl- and 4-hydrazinobut-2-enylphosphonium salts undergo spontaneous dehydrogenation leading to the corresponding hydrazones or diazenes, depending on the structure of the starting compounds or the reaction conditions. A possible mechanism of the trans-formations is discussed.
CARBONYL ADDITION REACTION BY MEANS OF β-SILYL- AND β-STANNYLPHOSPHOROUS YLIDES: DIASTEREOSELECTIVE E-PROPENYLATION OF α-CHIRAL ALDEHYDES.
Tsukamoto, Masamitsu,Iio, Hideo,Tokoroyama, Takashi
, p. 4561 - 4564 (2007/10/02)
E-propenylation of aldehydes using β-silyl- or β-stannylphosphorous ylides is devised, and extended to the diastereoselective reaction of α-methyl and α-alkoxy aldehydes.
