73010-42-1Relevant academic research and scientific papers
Cooperative Lewis acidity in borane-substituted fluorophosphonium cations
M?bus, Juri,Vom Stein, Thorsten,Stephan, Douglas W.
supporting information, p. 6387 - 6390 (2016/05/24)
A series of aryl-difluorophosphoranes are converted to give fluorophosphonium salts [Ph2PF(o-C6X4BR2)]+ (X = H, F; R = Cy, Mes). The proximity of the two weakly Lewis acidic fluorophosphonium and borane moieties results in enhanced Lewis acid catalytic reactivity.
Metal-free hydrogenation of electron-poor allenes and alkenes
Ines, Blanca,Palomas, David,Holle, Sigrid,Steinberg, Sebastian,Nicasio, Juan A.,Alcarazo, Manuel
, p. 12367 - 12369 (2013/02/22)
The poorer, the better: A metal-free catalytic procedure for the reduction of electron-poor allenes and alkenes has been developed. The method employs a frustrated Lewis pair based catalyst. 1,4-Diazabicyclo[2.2.2]octane (DABCO)/B(C6F5)3 was shown to be the best combination in optimization studies. Copyright
Electrochemical Reduction of Activated Carbon-Carbon Double Bonds. 3. 1,2 Phenyl Migration in the Reduction of Some 1,1-Diphenyl-Substituted Indenes
Farnia, Giuseppe,Marcuzzi, Franco,Melloni, Giovanni,Sandona, Giancarlo,Zucca, Maria Vincenza
, p. 918 - 923 (2007/10/02)
The reduction at a Hg electrode in DMF of 1,1,3-triphenylindene (1), 2-methyl-1,1,3-triphenylindene (2), and 1,1,2,3-tetraphenylindene (3) was carried out in order to check the occurrence of rearrangements of the reaction intermediates.The two-electron tw
