73022-89-6Relevant academic research and scientific papers
B(C6F5)3/Amine-Catalyzed C(sp)?H Silylation of Terminal Alkynes with Hydrosilanes: Experimental and Theoretical Studies
Ma, Yuanhong,Lou, Shao-Jie,Luo, Gen,Luo, Yong,Zhan, Gu,Nishiura, Masayoshi,Luo, Yi,Hou, Zhaomin
supporting information, p. 15222 - 15226 (2018/10/25)
Transition metal catalyzed C?H functionalization of organic compounds has proved to be a useful atom-efficient strategy in organic synthesis. In contrast, main-group-element-based catalytic processes for C?H functionalization have remained underexplored t
Sodium triethylborohydride as a catalyst for the dehydrogenative silylation of terminal alkynes with hydrosilanes
Skrodzki, Maciej,Witomska, Samanta,Pawlu?, Piotr
supporting information, p. 5948 - 5951 (2018/05/14)
The first example of sodium triethylborohydride-catalyzed C(sp)-H bond silylation is reported. The reaction of aromatic and aliphatic alkynes with aromatic hydrosilanes and hydrosiloxanes proceeded in a highly selective manner to afford dehydrocoupling pr
