73037-96-4Relevant articles and documents
Reactions of 1,1-Diarylethylenes and 1,1-Diarylimines with CF3OF
Patrick, Timothy B.,Cantrell, Gary L.,Inga, Sandra M.
, p. 1409 - 1413 (2007/10/02)
1,1-Diphenylethylene (1) reacts with CF3OF to give products 2-6 in a cationic process. 9-Ethylidenefluorene reacts with CF3OF to yield 8 and 10.Amitriptyline (12) furnished a difluoro adduct (13) in low yield.Benzophenone oxime (14) gave a Beckmann rearrangement product on reaction with CF3OF.Fluorenone anil (15) produced mainly fluorenone from reaction with CF3OF.Diazepam (16) gave a 1:1 adduct (18) with CF3OF.The adduct 18 reacted further to give an oxidation product (17).