73065-93-7Relevant academic research and scientific papers
SYNTHESIS AND 197Au-MOESSBAUER SPECTROSCOPIC STUDIES OF DIHALO(PENTAFLUOROPHENYL)(BIDENTATELIGAND)GOLD(III) COMPLEXES
Uson, Rafael,Laguna, Antonio,Orden, Maria U. de La
, p. 145 - 148 (2007/10/02)
Addition of a bidentate ligand (L-L=1,10-phenantroline, o-phenylenebis(dimethylarsine) to solutions of Au(C6F5)X2(tht) (X=Cl, Br; tht=tetrahydrothiophene) leads to potentially five-coordinate gold(III) derivatives. 197Au Moesbauer spectroscopy points, however, to four-coordinate square-planar complexes with a weak penta-coordination in the phen-containing derivatives.The complexes react with AgClO4 to give four-coordinate cationic complexes of the types ClO4 or (ClO4)2.
