7309-84-4Relevant academic research and scientific papers
FLUOROLACTONE AND METHOD FOR PRODUCING SAME
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Paragraph 0286, (2021/12/03)
The present disclosure provides, for example, a method that can produce a fluorolactone compound from hexafluoropropylene oxide or the like in a single step. The present disclosure relates to a method for producing a compound represented by formula (1): wherein two R1 are the same and each is a fluorine atom or a fluoroalkyl group, the method comprising step A of reacting a compound represented by formula (2): wherein R1 is as defined above, with a compound (3) represented by formula (3-1) or the like: wherein R31, R32, and R33 are the same or different and each is a hydrogen atom or a C1-10 alkyl group, or two of them are optionally linked to each other to form a ring optionally having one or more substituents, in the presence of a fluorine compound (4) represented by formula (4-1) or the like: [in-line-formulae]MHnFm(4-1)[/in-line-formulae] wherein M is a metal atom, n is 0 or 1, and the sum of the valence number of M and n is m, and an organic solvent, provided that the compound represented by formula (3) is excluded from the organic solvent.
Reaction of fluorosulfonyloxypentafluoroacetone in the presence of alkali metal fluorides
Sterlin,Avetisyan
experimental part, p. 1318 - 1320 (2010/10/04)
2-Fluorosulfonyloxytetrafluoropropionyl fluoride (3) is the product of isomerization of fluorosulfonyloxypentafluoroacetone (1). In the presence of CsF at low temperatures compound 3 forms 2-fluorosulfonyloxyperfluoropropoxy anion, and at -25 °C CsF catalyzes the decomposition of compounds 1 and 3 with the formation of trifluoropyruvoyl fluoride isolated as cyclodimer. ; 2009 Springer Science+Business Media, Inc.
