73093-24-0Relevant academic research and scientific papers
Iridium(I)-catalyzed vinylic C-H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron
Sasaki, Ikuo,Doi, Hana,Hashimoto, Toshiya,Kikuchi, Takao,Ito, Hajime,Ishiyama, Tatsuo
supporting information, p. 7546 - 7548 (2013/08/23)
Ir(i)-catalyzed C-H borylation of 1-cycloalkenecarboxylic derivatives with bis(pinacolato)diboron affords various alkenylboronates with functional groups in excellent yields. This reaction was also used in a one-pot borylation/Suzuki-Miyaura cross-coupling procedure.
Unusual products from dirhodium tetraacetylate-catalyzed decomposition of diazoacetylcycloalkanes
Ceccherelli, Paolo,Curini, Massimo,Marcotullio, Maria Carla,Pisani, Emanuela,Rosati, Ornelio,Wenkert, Ernest
, p. 8501 - 8506 (2007/10/03)
Rh2(OAc)4-assisted decompositions of diazoacetylcycloalkanes are shown to yield cycloalkylacetic acids (Wolff rearrangement), unexpected cycloalkylcarboxylic acids and bicyclic ketones (intramolecular C-H bond insertion). Rh2(OCOF3)4-promoted reactions, on the other hand, have furnished bicyclic ketones and ketene dimers.
