73113-52-7Relevant articles and documents
Radical C(sp2)-H Trifluoromethylation of Aldehydes in Aqueous Solution
Zhang, Pei,Shen, Haigen,Zhu, Lin,Cao, Weiguo,Li, Chaozhong
supporting information, p. 7062 - 7065 (2018/11/21)
The copper-mediated C(sp2)-H trifluoromethylation of aldehydes is described. The reaction of aldehydes with (bpy)Cu(CF3)3, Et3SiH, and K2S2O8 in aqueous acetone at room temperatu
The Synthesis and Liquid-Crystal Transition Temperatures of Some Fluoro-Substituted Benzonitriles
Kelly, Stephen M.,Schad, Hanspeter
, p. 1444 - 1452 (2007/10/02)
Various laterally fluoro-substituted benzonitriles have been prepared containing a trans-4-(n-alkyl)cyclohexane ring linked to the 4-position of the benzonitriles either through a methyleneoxy (-CH2O-) or an ethylene (-CH2CH2-) bridge.The bridging group links the benzonitrile and cyclohexane rings either directly or through an additional 1,4-bonded cyclohexane or benzene ring.The synthesis and liquid-crystal transition temperatures of these new compounds are described.In several cases the nematic-isotropic transition temperatures of F-substituted benzonitriles are found to be higher than those of the non-laterally substituted analogues.