73178-15-1Relevant academic research and scientific papers
Scalable electrochemical synthesis of diaryliodonium salts
Elsherbini, Mohamed,Moran, Wesley J.
, p. 4706 - 4711 (2021/06/11)
Cyclic and acyclic diaryliodonium are synthesised by anodic oxidation of iodobiaryls and iodoarene/arene mixtures, respectively, in a simple undivided electrolysis cell in MeCN-HFIP-TfOH without any added electrolyte salts. This atom efficient process does not require chemical oxidants and generates no chemical waste. More than 30 cyclic and acyclic diaryliodonium salts with different substitution patterns were prepared in very good to excellent yields. The reaction was scaled-up to 10 mmol scale giving more than four grams of dibenzo[b,d]iodol-5-ium trifluoromethanesulfonate (>95%) in less than three hours. The solvent mixture of the large-scale experiment was recovered (>97%) and recycled several times without significant reduction in yield.
IODONIUM ANALOGS AS INHIBITORS OF NADPH OXIDASES AND OTHER FLAVIN DEHYDROGENASES; FORMULATIONS THEREOF; AND USES THEREOF
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Paragraph 0107, (2015/11/17)
Disclosed herein are novel iodonium analogs having anticancer and anti-inflammatory activity.
Palladium catalyzed dual C-H functionalization of indoles with cyclic diaryliodoniums, an approach to ring fused carbazole derivatives
Wu, Yongcheng,Peng, Xiaopeng,Luo, Bingling,Wu, Fuhai,Liu, Bo,Song, Fenyun,Huang, Peng,Wen, Shijun
, p. 9777 - 9780 (2015/01/09)
Palladium(ii)-catalyzed dual C-H functionalization of indoles with cyclic diaryliodoniums was successfully achieved, providing a concise method to synthesize dibenzocarbazoles. In a single operation, two C-C bonds and one ring were formed. The reaction was ligand free and tolerated air and moisture conditions.
benzene, a Versatile Reagent for the Mild Oxidation of Aryl Iodides at the Iodine Atom by Ligand Transfer
Koser, Gerald F.,Wettach, Richard H.
, p. 1542 - 1543 (2007/10/02)
Treatment of a variety of aryl iodides with benzene (1) under mild conditions resulted in ligand transfer, and new arenes were obtained.However, with some substrates containing proximate functional groups cyclic iodonium salts and iodinanes resulted.The reaction between 1 and 2-iodothiophene took a distinctly different course.
