73181-27-8Relevant academic research and scientific papers
Synthesis and Reactions of t-Butyltellurocarbonyloxyalkanes
Barrett, Anthony G. M.,Read, Roger W.,Barton, Derek H. R.
, p. 2191 - 2195 (2007/10/02)
Reactions of t-butylchloromethylenedimethylammonium chloride with alcohols and sodium hydrogen telluride gave t-butyltellurocarbonyloxyalkanes. 3β-t-Butyltellurocarbonyloxy-5α-cholestane tC(=Te)OR> gave the ester (ButCO2R) with diphenylseleninic anhydride, and ethers (ButCH2OR) and tCHOR)2> with sodium hydrogen telluride.The ethers were formed via the oligotelluride tCHOR)2Ten; n=1-4> which with N-bromosuccinimide gave the imide tCHOR)-N(COCH2CH2CO)>.
