731850-93-4Relevant academic research and scientific papers
Structurally simple pyridine N-oxides as efficient organocatalysts for the enantioselective allylation of aromatic aldehydes
Pignataro, Luca,Benaglia, Maurizio,Annunziata, Rita,Cinquini, Mauro,Cozzi, Franco
, p. 1458 - 1463 (2007/10/03)
A series of structurally simple pyridine N-oxides have readily been assembled from inexpensive amino acids and tested as organocatalysts in the allylation of aldehydes with allyl(trichloro)silane to afford homoallylic alcohols. (S)-Proline-based catalysts
Asymmetric synthesis of 6-(2′,3′,4′,5′, 6′-pentafluorophenyl)-δ-lactones via "allyl"boranes via "allyl" boranes: Application for the synthesis of fluorinated analog of key pharmacophore of statin drugs
Ramachandran, P. Veeraraghavan,Padiya, Kamlesh J.,Rauniyar, Vivek,Reddy, M. Venkat Ram,Brown, Herbert C.
, p. 615 - 620 (2007/10/03)
Asymmetric "allyl"boration of pentafluorobenzaldehyde with various α-pinene based "allyl"boranes provides homoallylic alcohols in high de and ee; the alcohols have been converted into δ-lactones via acryloylation, ring-closing metathesis and hydrogenation
