73193-94-9

Upstream product

• 73193-93-8 4-(Carboethoxy)-1-methoxy-5-methyltricyclo<5.1.0.0^3,5>octane 
• 124518-71-4 2-chloro-1-methoxy-4,7-dimethylbicyclo<2.2.2>oct-5-en-2-carbonitrile 
• 69697-76-3 1-Methoxy-2,4-dimethylcyclohexa-1,4-diene 
• 124492-48-4 1-methoxy-4,7-dimethylbicyclo<2.2.2>oct-5-en-one 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 85999-34-4 (4,4-Dimethoxy-1,5-dimethyl-cyclohex-2-enyl)-acetic acid methyl ester 
• 73193-96-1 Methyl 1,5-Dimethyl-4-methoxy-2,4-cyclohexadienylacetate 

Relevant academic research and scientific papers

SYNTHESIS OF 4,4-DISUBSTITUTED CYCLOHEXENONES. PART 1. BAEYER-VILLIGER FRAGMENTATION OF 1-METHOXYBICYCLOOCT-5-ENONES.

The sodium acetate-buffered peracetic acid oxidation of various 1-methoxybicyclooct-5-enones (4a-f), and (14), prepared by hydrolysis of the adducts (3) derived from dihydroanisole derivatives (2) and 2-chloroacrylonitrile leads to 4-

Total Synthesis of (+/-)-9-Pupukeanone

A synthesis of (+/-)-9-pupukeanone (3) is described in which the pupukeanane skeleton is assembled by means of an intramolecular Diels-Alder reaction of 20 to 21.The vinyl ketone 20 was constructed via a sequence beginning from 8 and proceeding through di