7320-52-7

Basic information

• Product Name: 3-methyldibenzofuran
• Synonyms: 3-methyldibenzofuran;Dibenzofuran, 3-methyl-;Einecs 230-790-4;3-methyldibenzo[b,d]furan
• CAS NO: 7320-52-7
• Molecular Formula: C13H10O
• Molecular Weight: 182.2179
• EINECS: 230-790-4
• Mol File: 7320-52-7.mol
• Article Data: 15

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-methyldibenzofuran(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methyldibenzofuran(7320-52-7)
• EPA Substance Registry System: 3-methyldibenzofuran(7320-52-7)

Safety Data

• Hazardous Substances Data: 7320-52-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H10O/c1-9-6-7-13-11(8-9)10-4-2-3-5-12(10)14-13/h2-8H,1H3

Upstream product

• 624-31-7 4-tolyl iodide 
• 89466-08-0 2-hydroxyphenyl boronic acid 
• 615-42-9 1,2-Diiodobenzene 
• 1421367-18-1 6-diazo-3-methyl-2-cyclohexen-1-one 
• 583-55-1 1-Bromo-2-iodobenzene 
• 1620094-09-8 4'-methyl-2'-nitro-[1,1'-biphenyl]-2-ol 
• 5326-34-1 4-Bromo-3-nitrotoluene 
• 108-95-2 phenol 
• 3586-14-9 3-phenoxytoluene 
• 101043-55-4 2-(4-methylphenyl)phenol 
• 33094-66-5 2-nitro-benzofuran 
• 78-79-5 isoprene 
• 75420-78-9 3-nitrobenzofuran 
• 128916-10-9 2-Allyloxy-benzoic acid m-tolyl ester 

Downstream Products

• 29021-91-8 dibenzo[b,d]furan-3-carboxylic acid 

Relevant articles and documents

Copper-Catalyzed One-Pot Synthesis of Dibenzofurans, Xanthenes, and Xanthones from Cyclic Diphenyl Iodoniums

Oxygenation of cyclic diphenyl iodoniums (CDPIs) with varied medium-ring sizes has been fully investigated. This practical copper-catalyzed tandem reaction of CDPIs with water as the oxygen source enables the construction of derivatised dibenzofurans and xanthenes at moderate to good yields. Moreover, structurally important xanthones are also successfully accessed under the oxygenation conditions with additional TEMPO.

Microwave-Promoted Pd-Catalyzed Synthesis of Dibenzofurans from Ortho-Arylphenols

ortho-Aryl phenols, synthesized via protecting group free Suzuki–Miyaura coupling of ortho-halophenols and arene boronic acids, undergo a cyclization to dibenzofurans via oxidative C–H activation. The reaction proceeds under microwave irradiation in short reaction times using catalytic amounts of Pd(OAc)2 without additional ligands.

Chemoselective arylation of phenols with bromo-nitroarenes: Synthesis of nitro-biaryl-ols and their conversion into benzofurans and carbazoles

A series of electron withdrawing or donating group substituted phenols were chemoselectively arylated with various substituted bromo-nitroarenes using KOtBu at room temperature via an SNAr pathway. The synthesis of natural alkaloids (carbazoles), dibenzofurans, and a biaryl-indole was achieved from the synthesized nitro-biaryl-ols. This journal is the Partner Organisations 2014.