732247-45-9Relevant academic research and scientific papers
The synthesis of symmetrical bis-1,2,5-thiadiazole ligands
Philipp, Dean M.,Muller, Rick,Goddard, William A.,Abboud, Khalil A.,Mullins, Michael J.,Snelgrove, R. Vernon,Athey, Phillip S.
, p. 5441 - 5444 (2004)
We have been engaged in a search for coordination catalysts for the copolymerization of polar monomers (such as vinyl chloride and vinyl acetate) with ethylene. We have been investigating complexes of late transition metals with heterocyclic ligands. In this report we describe the synthesis of a symmetrical bis-thiadiazole. We have characterized one of the intermediates using single crystal X-ray diffraction. Several unsuccessful approaches toward 1 are also described, which shed light on some of the unique chemistry of thiadiazoles.
