73227-37-9Relevant academic research and scientific papers
Benzimidazolo-diazepines from 1,3-dienes and arenediazocyanides through a 1,3,4-tri-aza-Cope rerrangement
Rousselle, Daniel,Ryckmans, Thomas,Viehe, Heinz G.
, p. 5249 - 5258 (2007/10/02)
Cyclic and bicyclic 1-cyano-2-arylhydrazines were prepared from arene diazocyanides and 1,3-dienes. Some of them rearrange at room temperature through a 1,3,4-tri-aza-Cope rearrangement, followed by an intramolecular cyclisation, to afford benzimidazolo-d
Phase-Transfer Synthesis of Arenediazocyanides and Synthesis of Arenediazosulfones from Arenediazonium Cations and the Formation of Reduced Pyridazines by 2 + 4 Cycloaddition Reactions
Ahern, Michael F.,Leopold, Ahuva,Beadle, James R.,Gokel, George W.
, p. 548 - 554 (2007/10/02)
The remarkably versatile arenediazonium cations are also convenient to use and nondangerous when utilized as the BF4 or PF6 salts.Arenediazonium compounds have recently been shown to undergo the 2 + 4 Diels-Alder cycloaddition, but the reaction is solvent
