73311-45-2Relevant academic research and scientific papers
The Synthesis of NH Aldimines and Derivatives by Spontaneous and Base-catalysed Decomposition of Oxaziridines
Boyd, Derek R.,Coulter, Peter B.,Hamilton, Robert,Thompson, Norris T.,Sharma, Narain D.,Stubbs, Michael E.
, p. 2123 - 2128 (2007/10/02)
A range of oxaziridines containing N-methylene substituents has been synthesized by peracid oxidation of the corresponding fluorenylidene N-alkylamines.Spontaneous and tertiary amine base-catalysed decomposition of the oxaziridines into unstable NH aldimines and derivatives was observed.Acrylaldehyde, 2-methylacrylaldehyde, and benzaldehyde NH imines have been identified as initial products from decomposition of the corresponding oxaziridines. 2,4,6-Trialkylhexahydro-1,3,5-triazines, N,N'-dialkylidene-1,1-diaminoalkanes, N,N'-diarylidene-1,1-diaminoalkanes, and N-isobutylidene-2-methylpropenylamine were among the isolated products formed via the undetected alkyl aldehyde NH imines resulting from oxaziridine decomposition.
