73311-47-4Relevant academic research and scientific papers
A novel method for the synthesis of bis(1-diethoxyphosphorylalkyl)amines from diimines
Kaboudin, Babak,Jafari, Ehsan
, p. 3063 - 3066 (2008/02/08)
A novel and convenient method for the synthesis of bis(1- diethoxyphosphorylalkyl)amines has been developed. As described below, treatment of aromatic diimines with diethyl phosphite in the presence of chlorotrimethylsilane gave bis(1-diethoxyphosphorylalkyl)amines. This method is easy, rapid, and good-yielding for the synthesis of bis(1- diethoxyphosphorylalkyl)amines from simple starting materials. Georg Thieme Verlag Stuttgart.
A mild and highly efficient protocol for the one-pot synthesis of primary α-amino phosphonates under solvent-free conditions
Azizi, Najmedin,Rajabi, Fatemeh,Saidi, Mohammad R.
, p. 9233 - 9236 (2007/10/03)
Under solvent-free reaction conditions and in the presence of solid LiClO4 a novel and mild protocol for the one-pot, three-component synthesis of primary α-amino phosphonates from an aldehyde, hexamethyldisilazane and a trialkyl phosphite is described giving high yields and having short reaction times. The same products are obtained in very low yields, when the three-component reaction is carried out under microwave irradiation and in the absence of solid LiClO4. Examples of some prepared 1-aryl-N,N′-bis(arylidene)methanediamines are also described.
Microwave-assisted rapid and selective synthesis of cis- and trans-2,4,5-triarylimidazolines from aromatic aldehydes
Uchida, Hitoshi,Tanikoshi, Hirofumi,Nakamura, Shuichi,Reddy, Paidi Yella,Toru, Takeshi
, p. 1117 - 1120 (2007/10/03)
Microwave irradiation of a mixture of aromatic aldehydes and hexamethyldisilazane in the presence of a solid catalyst such as alumina afforded methanediamines which were efficiently converted to either cis- or trans-2,4,5-triarylimidazolines depending on the base used. A one-pot selective synthesis of cis- and transimidazolines from aromatic aldehydes was achieved under microwave irradiation.
Solvent-free efficient synthesis of 2,4,5-triarylimidazolines from aromatic aldehydes and hexamethyldisilazane
Uchida, Hitoshi,Shimizu, Takashi,Reddy, Paidi Yella,Nakamura, Shuichi,Toru, Takeshi
, p. 1236 - 1240 (2007/10/03)
A one-step preparation of 2,4,5-triarylimidazolines from aromatic aldehydes was accomplished by heating with hexamethyldisilazane under solvent-free conditions. This reaction provides a convenient preparative method for triarylimidazolines having a variety of aryl groups.
