73323-61-2Relevant academic research and scientific papers
Stereochemistry of Halogenation of Nitronate Adducts from 4-Methoxy-1-nitronaphthalene and RMgX to 1-Halogeno-2-alkyl-4-methoxy-1-nitro-1,2-dihydronaphthalenes and of Subsequent Elimination to Alkylhalogenonaphthalenes. Crystal Structure of a Tetrahydrona
Bartoli, Giuseppe,Bosco, Marcella,Foresti, Elisabetta,Pradella, Gabriele
, p. 3109 - 3113 (2007/10/02)
Studies on the stereochemical aspects of the reactivity of nitronate adducts from RMgX and nitroarenic systems have been extended to their reaction with electrophilic reagents other than H3O+.The reaction of C-bromination of the 1,4-adducts fro
Stereochemical Study on Nitro Tautomerization of Nitronate Adducts from Conjugate Addition of RMgX to a 4-Methoxy-1-nitronaphthalene System
Bartoli, Giuseppe,Bosco, Marcella,Baccolini, Graziano
, p. 2649 - 2653 (2007/10/02)
Addition of RMgX to 4-methoxy-1-nitronaphthalene (1) leads to formation of nitronate 1,4 adduct (2) together with lesser amounts of 1,6 addition product (3).On treatment with aqueous acetate-acetic acid buffer, 2 is converted into a nitronate anion which
