73357-41-2Relevant academic research and scientific papers
Oxidative Desymmetrization of Isoindolines Realized by tert -Butyl Nitrite (TBN) Initiated Radical sp 3C-H Activation Relay (CHAR)
Sun, Zheng,Shao, Yu,Zhang, Shuwei,Zhang, Yuxian,Yuan, Yu,Jia, Xiaodong
, p. 1663 - 1671 (2021/02/01)
An oxidative desymmetrization of isoindolines was realized by TBN initiated radical sp 3C-H activation relay (CHAR), providing a series of ω-hydroxylactams in high yields. This reaction exhibits broad substrate scope and functional group tolerance, and even N -alkyl iso-indolines can be well tolerated. The mechanistic study shows that the C-H bond oxidation, dioxygen trapping and intramolecular 1,5-H shift might be the key steps to achieve the oxidative desymmetrization.
Visible-light induced isoindoles formation to trigger intermolecular diels-alder reactions in the presence of air
Lin, Chao,Zhen, Le,Cheng, Yong,Du, Hong-Jin,Zhao, Hui,Wen, Xiaoan,Kong, Ling-Yi,Xu, Qing-Long,Sun, Hongbin
supporting information, p. 2684 - 2687 (2015/06/16)
Visible-light induced isoindole formation triggered an intermolecular Diels-Alder reaction with dienophiles such as acetylenedicarboxylate and maleimides in the presence of air. The reaction resulted in excellent diastereoselctivity and high yields under
CHARGE-TRANSFER COMPLEXES OF ISOINDOLINES WITH 1,4-BENZOQUINONES
Mourad, Aboul-fetouh E.,Nour-el-din, Ahmed M.,Hassan, Alaa A.,Doepp, Dietrich
, p. 1045 - 1052 (2007/10/02)
Charge-transfer (CT) complexes of various N-arylisoindolines as donors with 1,4-benzoquinones as ?-acceptors have been studied spectrophotometrically.Effects of substituents
