73372-15-3Relevant academic research and scientific papers
Dual Rh?Ru Catalysts for Reductive Hydroformylation of Olefins to Alcohols
Rodrigues, Fábio M. S.,Kucmierczyk, Peter K.,Pineiro, Marta,Jackstell, Ralf,Franke, Robert,Pereira, Mariette M.,Beller, Matthias
, p. 2310 - 2314 (2018/07/31)
An active and selective dual catalytic system to promote domino hydroformylation–reduction reactions is described. Apart from terminal, di- and trisubstituted olefins, for the first time the less active internal C?C double bond of tetrasubstituted alkenes can also be utilized. As an example, 2,3-dimethylbut-2-ene is converted into the corresponding n-alcohol with high yield (90 %) as well as regio- and chemoselectivity (>97 %). Key for this development is the use of a combination of Rh complexes with bulky monophosphite ligands and the Ru-based Shvo's complex. A variety of aromatic and aliphatic alkenes can be directly used to obtain mainly linear alcohols.
METHOD FOR PRODUCING α-METHYL-γ-BUTYROLACTONE
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Paragraph 0042, (2017/01/02)
PROBLEM TO BE SOLVED: To provide a producing method capable of obtaining a high-purity α-methyl-γ-butyrolactone. SOLUTION: There is provided a method for producing α-methyl-γ-butyrolactone, in producing α-methyl-γ-butyrolactone represented by following formula (1), including the steps of: adding an organic base or a salt thereof into a reaction liquid; and distilling the reaction liquid. COPYRIGHT: (C)2015,JPOandINPIT
