733752-91-5Relevant academic research and scientific papers
The preparation and complexation of 5,10-bis(diphenylphosphino)phenazine
Rodriguez I Zubiri, Mireia,Milton, Heather L.,Cole-Hamilton, David J.,Slawin, Alexandra M.Z.,Woollins, J. Derek
, p. 201 - 203 (2004)
Reaction of 5,10-dihydrophenazine with two equivalents of Ph 2PCl, in the presence of n-BuLi at -78°C in thf gives Ph 2PN(C6H4)(C6H4)NPPh 2 (1) which can be oxidised with selenium to Ph2P(Se) N(C6H4)(C6 H4)NP(Se)Ph2 (2) or coordinated with Pt(II) in cis-[PtCl2{Ph2PN(C 6H4)(C6H4)NPPh2}] (3) The structure of 3 reveals a severely distorted (non-planar) phenazine backbone.
