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Chemistry of Unsymmetrical Phosphorus Ligands: Part I - Synthesis and Spectroscopic Properties of Adducts of Mercury(II) Halides with (Diphenylphosphinomethyl)diphenylphosphine Chalcogenides
Lobana, T. S.,Sharma, P. K.
, p. 784 - 785 (2007/10/02)
Reactions of unsymmetrical phosphorus ligands, Ph2P(X)CH2PPh2 (X = S, Se) (L-L), with mercury(II) halides in ethanol or ethanol-chloroform mixture give 1:1 adducts of the type HgX2(L-L).The adducts have been characterized by elemental analysis, molar conductance, IR and far IR spectral data.The mass spectrum of one adduct has been also obtained.The adducts have been assigned tetrahedral structures.
